Machine Learning

What can Attribution Methods show us about Chemical Language Models?
S. Hödl, T. Kachman, Y. Bachrach, W. T. S. Huck, W. E. Robinson Digital Discovery 2024, in press, DOI: 10.1039/D4DD00084F

Chemical Reaction Systems

Chemical reservoir computation in a self-organizing reaction network
M. G. Baltussen, T. J. de Jong, Q. Duez, W. E. Robinson, W. T. S. Huck Nature 2024, 631, 549-555, DOI: 10.1038/s41586-024-07567-x

Dynamic Environmental Conditions Affect the Composition of a Model Prebiotic Reaction Network
P. van Duppen, E. Daines, W. E. Robinson, W. T. S. Huck J. Am. Chem. Soc. 2023, 145, 7559-7568, DOI: 10.1021/jacs.3c00908

Environmental conditions drive self-organization of reaction pathways in a prebiotic reaction network
W. E. Robinson, E. Daines, P. van Duppen, T. de Jong and W. T. S. Huck Nature Chemistry 2022, 14, 623–631, DOI: 10.1038/s41557-022-00956-7

Artificial Photosynthesis

Reversible and Selective Interconversion of Hydrogen and Carbon Dioxide into Formate by a Semiartificial Formate Hydrogenlyase Mimic
K. P. Sokol, W. E. Robinson, A. R. Oliveira, S. Zacarias, C.-Y. Lee, C. Madden, A. Bassegoda and J. Hirst J. Am. Chem. Soc. 2019, 141, 17498-17502, DOI: 10.1021/jacs.9b09575

Interfacing Formate Dehydrogenase with Metal Oxides for the Reversible Electrocatalysis and Solar‐Driven Reduction of Carbon Dioxide
M. Miller, W. E. Robinson, A. R. Oliveira, N. Heidary, N. Kornienko, J. Warnan, I. A. C. Pereira and E. Reisner Angew. Chem. Int. Ed. 2019, 58, 4601–4605, DOI: 10.1002/anie.201814419

Advancing Techniques for Investigating the Enzyme-Electrode Interface
N. Kornienko, K. H. Ly, W. E. Robinson, N. Heidary, J. Z. Zhang and E. Reisner Acc. Chem. Res. 2019, 52, 1439-1448 , DOI: 10.1021/acs.accounts.9b00087

Photoreduction of CO2 with a Formate Dehydrogenase Driven by Photosystem II Using a Semi-Artificial Z-Scheme Architecture
K. P. Sokol, W. E. Robinson, A. R. Oliveira, J. Warnan, M. M. Nowaczyk, A. Ruff, I. A. C. Pereira and E. Reisner J. Am. Chem. Soc. 2018, 140, 16418–16422, DOI: 10.1021/jacs.8b10247

Bias-Free Photoelectrochemical Water Splitting with Photosystem II on a Dye-Sensitized Photoanode Wired to Hydrogenase
K. P. Sokol, W. E. Robinson, J. Warnan, N. Kornienko, M. M. Nowaczyk, A. Ruff, J. Z. Zhang and E. Reisner, Nature Energy 2018, 3, 944–951, DOI: 10.1038/s41560-018-0232-y

CO2 Reduction/Enzyme Electrocatalysis

Understanding How the Rate of C–H Bond Cleavage Affects Formate Oxidation Catalysis by a Mo-Dependent Formate Dehydrogenase
W. E. Robinson, A. Bassegoda, J. N. Blaza, E. Reisner and J. Hirst J. Am. Chem. Soc. 2020, 142, 12226–12236, DOI: 10.1021/jacs.0c03574

Oxidation-State-Dependent Binding Properties of the Active Site in a Mo-Containing Formate Dehydrogenase
W. E. Robinson, A. Bassegoda, E. Reisner and J. Hirst J. Am. Chem. Soc. 2017, 139, 9927–9936, DOI: 10.1021/jacs.7b03958